WebDynamic chiralities are equally crucial in switchable stereoselectivity, switchable asymmetric catalysis and enantioselective separation. Herein, we limit our discussion to recent advances on stimuli-induced chiroptical switching of axial, helical, and planar chirality in response to external stimuli. WebApr 13, 2024 · This photochromic process caused variations in the electronic structure and ligand conformation, and led to the presence of light-responsive optical (UV and PL) and chiroptical (ECD and CPL) switching properties. The helicate may, therefore, be considered as a completely reversible +/− ECD and on/off CPL switch.
Off–off–on chiroptical property switching of a pyrene …
WebSep 24, 2005 · One of the first examples of a property change achieved through a controlled large-amplitude translational motion in a rotaxane is described; a novel type of chiroptical switch is described, in which light-induced translation of the macrocycles along the thread of a [2]rotaxane produces a strong induced circular dichroism (ICD) response only when … WebAug 18, 2024 · Chemically Fueled Three-State Chiroptical Switching Supramolecular Gel with Temporal Control Chemically Fueled Three-State Chiroptical Switching Supramolecular Gel with Temporal Control J Am Chem Soc. 2024 Aug 18;143 (32):12650-12657. doi: 10.1021/jacs.1c05183. Epub 2024 Aug 5. Authors bio roundup
Acidichromism and chiroptical switch based on the self-assembly …
WebApr 30, 2004 · A dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-N(pyridine) coordinative bond controls the … WebMar 6, 2024 · The stepwise assembly process successfully facilitated an “off–off–on” chiroptical switching process of a pyrene luminophore controlled by the concentration of Zn 2+. The resulting pyrene-bridged helicates exhibit high performance in terms of a dissymmetry factor of circular dichroism ( g CD = 0.006) and circularly polarized ... WebThe binding of large anions favors a chiral double helix and activates light-driven switching into racemic single helices thereby modulating the quaternary structure and chiroptical activity. This work shows how complex multifunctional outcomes emerge when allosteric changes in structure are expressed in intrinsically functional foldamers. dairy free gluten free thanksgiving